Published in
Royal Society of Chemistry, RSC Advances, 1(13), p. 14-24, 2023
DOI: 10.1039/d2ra05806e
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Exploring fluoride effects in sterically enhanced cobalt ethylene polymerisation catalysts; a combined experimental and DFT study
Journal article published in 2023 by
Zilong Li 
,
Yanping Ma ,
Tian Liu,
Qiuyue Zhang ,
Gregory A. Solan,
Tongling Liang ,
Wen-Hua Sun
,
Yanping Ma ,
Tian Liu,
Qiuyue Zhang ,
Gregory A. Solan,
Tongling Liang ,
Wen-Hua Sun
This paper is made freely available by the publisher.
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Abstract
The F-substituted cobalt complexes decorated with benzhydryl groups displayed high activity in ethylene polymerization. Through DFT and experimental findings, the combination of remote fluorides and steric bulk has enhanced catalytic activity and thermal stability.