Static and dynamic autocorrelations of charge density, composed of positive point ions and instantaneous distribution of electron density, are studied in liquid Li in a pressure range from ambient to 186 GPa using ab initio molecular dynamics simulations. It is shown analytically that the long-wavelength limit of the charge-charge static structure factor SQQ(k) of liquid metals is proportional to k4. Time-dependent charge-charge correlations in liquid Li at low pressures show identical relaxation as the density-density time correlation functions, in complete agreement with the linear response theory, whereas at extreme pressures we observed different relaxation of the charge and density autocorrelations. The static and dynamic properties of a part of electron density, that corresponds to the nonspherical distribution around ions, are discussed. © 2014 American Physical Society.