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Wiley, Angewandte Chemie International Edition, 43(46), p. 8258-8261, 2007

DOI: 10.1002/anie.200700610

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Buckybowls on Metal Surfaces: Symmetry Mismatch and Enantiomorphism of Corannulene on Cu(110)

Journal article published in 2007 by Manfred Parschau, Roman Fasel, Karl-Heinz Ernst ORCID, Oliver Gröning, Louis Brandenberger, Richard Schillinger, Thomas Greber, Ari P. Seitsonen ORCID, Yao-Ting Wu, Jay S. Siegel
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Abstract

Fivefold versus twofold: Symmetry-breaking interactions in the monolayer of the buckybowl corannulene on Cu(110) lead to the formation of extended mirror domains (see picture). The molecules are adsorbed in a tilted geometry with the bowl opening pointing away from the surface.