Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction
Journal article published in 2015 by
Abdelilah Takfaoui,
Rachid Touzani 
,
Jean-François Soulé,
Pierre H. Dixneuf,
Henri Doucet
,
Jean-François Soulé,
Pierre H. Dixneuf,
Henri Doucet
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Abstract
The palladium-catalyzed C-C bond formation via direct arylation of free-amine-substituted polyfluoroaniline derivs. proceeds in moderate to high yields with a variety of aryl bromides. The nature of the base was found to be crucial to promote the direct arylation with inhibition of the amination reaction. [on SciFinder(R)]