Published in
Royal Society of Chemistry, Chemical Science, 12(14), p. 3265-3269, 2023
DOI: 10.1039/d3sc00851g
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Helical fluxionality: numerical frustration drives concerted low-barrier screw motions of a tricopper cluster
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Abstract
An uneven distribution of ligand donor atoms and metal centers of a double-helical trinuclear complex drives a hitherto unknown type of fluxional motion taking a spiral path with an extraordinarily low energy barrier.