Published in
Royal Society of Chemistry, Chemical Science, 12(14), p. 3270-3276, 2023
DOI: 10.1039/d2sc07063d
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Fine-tuning of the size of supramolecular nanotoroids suppresses the subsequent catenation of nano-[2]catenane
Journal article published in 2023 by
Hiroki Itabashi,
Sougata Datta 
,
Ryohei Tsukuda,
Martin J. Hollamby ,
Shiki Yagai
,
Ryohei Tsukuda,
Martin J. Hollamby ,
Shiki Yagai
This paper is made freely available by the publisher.
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Abstract
The reduction in the inner diameter of the nanotoroids of a π-conjugated barbiturate monomer results in nano-[2]catenanes in a high yield due to enhanced secondary nucleation and subsequent steric suppression of further catenation.