American Association for the Advancement of Science, Science, 6678(383), p. 81-85, 2024
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Isolable singlet carbenes have universally adopted a σ 2 π 0 electronic state, making them σ-donors and π-acceptors. We present a rhodium-coordinated, cationic cyclic diphosphinocarbene with a σ 0 π 2 ground state configuration. Nuclear magnetic resonance spectroscopy studies show a carbene carbon chemical shift below −30.0 parts per million. X-ray crystallography reveals a planar RhP 2 C configuration. Quantum chemical calculations rationalize how σ-electron delocalization/donation and π-electron negative hyperconjugation together stabilize the formally vacant σ orbital and the filled π orbital at the carbene center. In contrast to traditional carbene counterparts this carbene can undergo synthetic transformations with both a Lewis base and a silver salt, producing a Lewis acid/base adduct and a silver π-complex, respectively. Exhibiting ambiphilic reactivity, it can also form a ketenimine through reaction with an isocyanide.