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Royal Society of Chemistry, Chemical Science, 1(13), p. 149-158, 2022

DOI: 10.1039/d1sc04248c

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A short, versatile route towards benzothiadiazinyl radicals

Journal article published in 2022 by Andryj M. Borys ORCID, Ewan R. Clark ORCID, Paul J. Saines ORCID, Antonio Alberola ORCID, Jeremy M. Rawson ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A family of 1,2,4-benzothiadiazinyl radicals are accessible from 1,2,4-benzothiadiazine 1-chlorides which can be prepared in a single step by treatment of N-arylamidines in neat thionyl chloride at reflux.