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CSIRO Publishing, Australian Journal of Chemistry, 9(75), p. 631-635, 2022

DOI: 10.1071/ch21335

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An icosanuclear silver(I) cluster supported by bis(thiosemicarbazonato) ligands

Journal article published in 2022 by Brett M. Paterson ORCID, Jonathan M. White ORCID, Paul S. Donnelly ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis and structural characterisation of an icosanuclear silver(I) cluster complex is reported here. The complex includes twenty silver(I) ions supported by eighteen bis(thiosemicarbazonato) ligands. The cluster of silver(I) ions involves several close Ag⋯Ag contacts suggesting some degree of argentophilic interactions and the bis(thiosemicarbazonato) ligands are present in three different conformations highlighting the ability of thiosemicarbazone ligands to coordinate to metal ions in different modes.