The origin of heavier elements than iron is still under discussion, and recent studies suggest that the contribution of the r-process in neutron star mergers is dominant. Future modeling of such processes will require a huge amount of spectroscopic data on multiply charged ions of heavy elements. However, these experimental data are extremely scarce for heavy elements. In this work, we have performed the measurements of charge exchange spectroscopy for multiply charged Er ions in the visible light range. We report observed emission lines from multiply charged Er ions and their identification based on theoretical estimates.