Abstract We present position–position–velocity (PPV) cubes of the physical and chemical properties of the molecular medium in the central 1.2 kpc region of the active galaxy NGC 613 at a PPV resolution of 0.″8 × 0.″8 × 10 km s⁻¹ (0.″8 = ∼68 pc). We used eight molecular lines (¹³CO(1–0), C¹⁸O(1–0), HCN(1–0), HCO⁺(1–0), CS(2–1), HCN(4–3), HCO⁺(4–3), and CS(7–6)) obtained with the Atacama Large Millimeter/submillimeter Array. Non-LTE calculation with hierarchical Bayesian inference was used to construct PPV cubes of the gas kinetic temperature (T _kin), molecular hydrogen volume density ( n H 2 ), column densities ( N H 2 ), and fractional abundances of four molecules (¹²C¹⁸O, HCN, HCO⁺, and CS). The derived n H 2 , N H 2 , and T _kin ranged from 10^3.21−3.85 cm⁻³, 10^20.8−22.1 cm⁻², and 10^2.33−2.64 K, respectively. Our first application of the non-LTE method with the hierarchical Bayesian inference to external galaxies yielded compatible results compared with the previous studies of this galaxy, demonstrating the efficacy of this method for application to other galaxies. We examined the correlation between gas surface density Σ H 2 (converted from N H 2 ) and the star formation rate Σ_SFR obtained from the 110 GHz continuum flux map and found two distinct sequences in the Σ H 2 –Σ_SFR diagram; the southwestern subregion of the star-forming ring exhibited a ∼0.5 dex higher star formation efficiency (SFE; Σ_SFR/ Σ H 2 ) than the eastern subregion. However, they exhibited no systematic difference in n H 2 , which is often argued as a driver of SFE variation. We suggest that the deficiency of molecular gas in the southwestern subregion, where no significant gas supply is evident along the offset ridges in the bar, is responsible for the elevated SFE.