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Royal Society of Chemistry, Chemical Science, 41(13), p. 12239-12244, 2022

DOI: 10.1039/d2sc03073j

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[2 + 2] Cycloaddition of phosphaalkenes as a key step for the reductive coupling of diaryl ketones to tetraaryl olefins

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Mechanistically distinct from all other carbonyl-to-alkene conversion methodologies, the [2 + 2] cycloaddition of phosphaalkene intermediates is established as the enabling elementary step in this transformation.