Highly Conjugated Bis(benzo[b]phosphole)‐P‐oxides: Synthesis and Electrochemical, Optical, and Computational Studies
Journal article published in 2022 by
Nicolas D'Imperio,
Valentina Pelliccioli,
Sara Grecchi,
Alberto Bossi,
Francesca Vasile,
Silvia Cauteruccio,
Anna I. Arkhypchuk,
Arvind Kumar Gupta,
Andreas Orthaber 
,
Sascha Ott ,
Emanuela Licandro
,
Sascha Ott ,
Emanuela Licandro
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Abstract
AbstractThe first examples of a π‐conjugated benzo[b]phosphole P‐oxide in which two phosphole P‐oxide units are connected by a carbon‐carbon double bond are described. The molecules are synthesized as E isomers with respect to the carbon‐carbon double bond and exist as stable cis and trans isomers (chiral and meso one respectively) relatively to the two stereogenic P atoms. The optical and electrochemical properties of both isomers have been investigated by experiment and computations.