Nowadays, there is an increased demand to develop alternative non-plastic packaging to be used in the food industry. The most popular biodegradable films are cellulose and poly(lactic acid) (PLA); however, there is still the need to increase their UV absorption to protect the packaging content. In this work, we have covered those biodegradable films with thin coatings based on carbon dots (CDs) dispersed in polyvinyl alcohol (PVA) deposited by spin- or spray-coating techniques. We report a strong increase in the UV light-absorbing properties, together with a detailed morphological characterization; moreover, we show the results of a new microscopy and spectral imaging technique applied to the coated samples. The scientific and technological novelty of this approach is the possibility of characterizing large areas of the material surface by the simultaneous detection of PL spectra in all the pixels of a highly spatially-resolved two-dimensional (2D) map of the surface. We report UV-excited PL maps whose detailed information allows us to clearly identify regions with different spectral behaviors and to compare their characteristic signals for different CDs:PVA deposition techniques.