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Published in

Royal Society of Chemistry, Materials Advances, 11(2), p. 3620-3628, 2021

DOI: 10.1039/d1ma00196e

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Structural evolution, optical gap and thermoelectric properties of CH<sub>3</sub>NH<sub>3</sub>SnBr<sub>3</sub> hybrid perovskite, prepared by mechanochemistry

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

From the cubic phase at RT, three superstructures are identified down to 120 K result from the octahedral SnBr6 tilting and the stereochemical effect of Sn2+ lone pair. The Seebeck coefficient is ∼2000 μV K−1 at RT.