Published in

Wiley, Advanced Electronic Materials, 12(7), 2021

DOI: 10.1002/aelm.202100380

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Direct Visualization of Anti‐Ferroelectric Switching Dynamics via Electrocaloric Imaging

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

AbstractThe large electrocaloric coupling in PbZrO3 allows using high‐speed infrared imaging for visualizing anti‐ferroelectric switching dynamics via the associated temperature change. It is found that in ceramic samples of homogeneous temperature and thickness, switching is fast due to the generation of multiple nucleation sites, with devices responding in the millisecond range. By introducing gradients of thickness, however, it is possible to change the dynamics to propagation limited, whereby a single‐phase boundary sweeps across the sample like a cold front, at a speed of ≈20 cm s−1. Additionally, introducing thermostatic temperature differences between two sides of the sample enables the simultaneous generation of a negative electrocaloric effect on one side and a positive one on the other, yielding a Janus‐like electrocaloric response.