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Royal Society of Chemistry, Chemical Science, 5(14), p. 1301-1307, 2023

DOI: 10.1039/d2sc06573h

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C(sp<sup>3</sup>)–H cyanation by a formal copper(iii) cyanide complex

Journal article published in 2023 by Jamey K. Bower, Maxwell S. Reese, Ilia M. Mazin ORCID, Lina M. Zarnitsa, Andrew D. Cypcar, Curtis E. Moore, Alexander Y.-U. Sokolov ORCID, Shiyu Zhang ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A formal copper(iii) cyanide complex and its C–H cyanation reactivity are reported. The redox potentials of substrates, instead of C–H bond dissociation energies, were found to be the key determinant of the rates of PCET.