Published in
Royal Society of Chemistry, Chemical Science, 43(12), p. 14494-14498, 2021
DOI: 10.1039/d1sc04369b
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Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
Journal article published in 2021 by
Jing Xiang 
,
Min Peng,
Yi Pan ,
Li-Juan Luo,
Shun-Cheung Cheng,
Xin-Xin Jin,
Shek-Man Yiu,
Wai-Lun Man ,
Chi-Chiu Ko ,
Kai-Chung Lau ,
Tai-Chu Lau
,
Min Peng,
Yi Pan ,
Li-Juan Luo,
Shun-Cheung Cheng,
Xin-Xin Jin,
Shek-Man Yiu,
Wai-Lun Man ,
Chi-Chiu Ko ,
Kai-Chung Lau ,
Tai-Chu Lau
This paper is made freely available by the publisher.
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Abstract
The visible light-induced N-dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex has been investigated. We provide definitive evidence that these reactions occur via an ET/PT mechanism.