Published in

American Institute of Physics, The Journal of Chemical Physics, 7(155), 2021

DOI: 10.1063/5.0058172

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Diffusion, phase behavior, and gelation in a two-dimensional layer of colloids in osmotic equilibrium with a polymer reservoir

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The addition of enough non-adsorbing polymers to an otherwise stable colloidal suspension gives rise to a variety of phase behaviors and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a study of these phenomena in a two-dimensional layer of colloids. The three-dimensional phenomenology of crystal–fluid coexistence is reproduced, but gelation takes a novel form, in which the strands in the gel structure are locally crystalline. We compare our findings with a previous simulation and theory and find substantial agreement.