AbstractIn this study we explored the environmental conditions hypothesized to induce a dominant charge structure in thunderstorms in the province of Cordoba, Argentina, during the RELAMPAGO‐CACTI (Remote sensing of Electrification, Lightning, And Mesoscale/microscale Processes with Adaptive Ground Observations‐Clouds, Aerosols, Complex Terrain Interactions) field campaigns. Hypothesized environmental conditions are thought to be related to small warm cloud residence time and warm rain growth suppression, which lead to high cloud liquid water contents in the mixed‐phase zone, contributing to positive charging of graupel and anomalous charge structure storms. Data from radiosondes, a cloud condensation nuclei (CCN) ground‐based instrument and reanalysis were used to characterize the proximity inflow air of storms with anomalous and normal charge structures. Consistent with the initial hypothesis, anomalous storms had small warm cloud depth caused by dry low‐level humidity and low 0°C height. Anomalous storms were associated with lower CCN concentrations than normal storms, an opposite result to the initial expectation. High CAPE is not an important condition for the development of anomalous storms in Argentina, as no clear pattern could be found among the different parameters calculated for updraft proxy that would be consistent with the initial hypothesis.