Published in
Royal Society of Chemistry, Chemical Science, 26(13), p. 7907-7913, 2022
DOI: 10.1039/d2sc01088g
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Between imide, imidyl and nitrene – an imido iron complex in two oxidation states
Journal article published in 2022 by
Sascha Reith 
,
Serhiy Demeshko,
Beatrice Battistella ,
Alexander Reckziegel,
Christian Schneider ,
Andreas Stoy,
Crispin Lichtenberg ,
Franc Meyer ,
Dominik Munz ,
C. Gunnar Werncke
,
Serhiy Demeshko,
Beatrice Battistella ,
Alexander Reckziegel,
Christian Schneider ,
Andreas Stoy,
Crispin Lichtenberg ,
Franc Meyer ,
Dominik Munz ,
C. Gunnar Werncke
This paper is made freely available by the publisher.
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Abstract
A pair of trigonal imido iron complexes ([Fe(NMes)L2]0,−) in two oxidation states is reported. The anionic complex K{crypt.222}[Fe(NMes)L2] is best described as an iron(ii) imide.