Published in

Wiley, Angewandte Chemie, 24(135), 2023

DOI: 10.1002/ange.202302844

Wiley, Angewandte Chemie International Edition, 24(62), 2023

DOI: 10.1002/anie.202302844

Links

Tools

Export citation

Search in Google Scholar

Peroxygenase‐Catalysed Selective Oxidation of Silanes to Silanols

Journal article published in 2023 by Xiaomin Xu, Jacob M. A. van Hengst ORCID, Yejia Mao, Mireia Martinez ORCID, Sergi Roda ORCID, Martin Floor ORCID, Victor Guallar ORCID, Caroline E. Paul ORCID, Miguel Alcalde ORCID, Frank Hollmann ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

AbstractA peroxygenase‐catalysed hydroxylation of organosilanes is reported. The recombinant peroxygenase from Agrocybe aegerita (AaeUPO) enabled efficient conversion of a broad range of silane starting materials in attractive productivities (up to 300 mM h−1), catalyst performance (up to 84 s−1 and more than 120 000 catalytic turnovers). Molecular modelling of the enzyme‐substrate interaction puts a basis for the mechanistic understanding of AaeUPO selectivity.