Published in
Royal Society of Chemistry, Chemical Science, 17(12), p. 6153-6158, 2021
DOI: 10.1039/d1sc00668a
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Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds
Journal article published in 2021 by
Dieuwertje K. Modder 
,
Chad T. Palumbo ,
Iskander Douair ,
Rosario Scopelliti ,
Laurent Maron ,
Marinella Mazzanti
,
Chad T. Palumbo ,
Iskander Douair ,
Rosario Scopelliti ,
Laurent Maron ,
Marinella Mazzanti
This paper is made freely available by the publisher.
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Abstract
Both a masked and the actual complex [U(ii){N(SiMe3)2}3]+ effect the reduction of azobenzene to yield a U(vi) bis-imido species providing the first example of a “clear-cut” metal centred four-electron reduction in f-element chemistry.