AbstractTerrestrial ecosystems in China receive the world’s largest amount of reactive nitrogen (N) deposition. Recent controls on nitrogen oxides (NO_x = NO + NO₂) emissions in China to tackle air pollution are expected to decrease N deposition, yet the observed N deposition fluxes remain almost stagnant. Here we show that the effectiveness of NO_x emission controls for reducing oxidized N (NO_y = NO_x + its oxidation products) deposition is unforeseen in Eastern China, with one-unit reduction in NO_x emission leading to only 55‒76% reductions in NO_y-N deposition, as opposed to the high effectiveness (around 100%) in both Southern China and the United States. Using an atmospheric chemical transport model, we demonstrate that this unexpected weakened response of N deposition is attributable to the enhanced atmospheric oxidizing capacity by NO_x emissions reductions. The decline in N deposition could bear a penalty on terrestrial carbon sinks and should be taken into account when developing pathways for China’s carbon neutrality.