Dissemin is shutting down on January 1st, 2025

Published in

arXiv, 2022

DOI: 10.48550/arxiv.2206.13552

American Physical Society, Physical Review B, 17(106), 2022

DOI: 10.1103/physrevb.106.174105

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Generalized relation between electromechanical responses at fixed voltage and fixed electric field

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We present a general relation between the electromechanical couplings of infinitesimal strain and electric field to arbitrary order, measured at fixed voltage and at fixed electric field. We show that the improper response at fixed field can be written as the strain derivative of the $n^{\text{th}}$ order susceptibility tensor, and the proper response at fixed voltage drop can be written as the response at fixed field plus corrections for dilations and 90$^{∘}$ rotations induced by strain. Our theory correctly reproduces the proper piezoelectric response and we go beyond with the electrostrictive response. We present first-principles calculations of the improper electrostrictive response at fixed field, and illustrate how the correction is used to obtain the proper response at fixed voltage. This distinction is of high importance given the recent interest in giant electrostrictors exhibiting electromechanical responses as large as the piezoelectric ones.