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Royal Society of Chemistry, Chemical Science, 23(12), p. 8157-8164, 2021

DOI: 10.1039/d1sc00534k

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Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η<sup>7</sup>-B<sub>7</sub>)-B-BO]<sup>−</sup>

Journal article published in 2021 by Wen-Juan Tian ORCID, Wei-Jia Chen ORCID, Miao Yan, Rui Li, Zhi-Hong Wei, Teng Chen, Qiang Chen, Hua-Jin Zhai ORCID, Si-Dian Li ORCID, Lai-Sheng Wang ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The global minimum of the B9O− cluster is found to have an umbrella-like structure, where the central B atom exhibits transition-metal-like bonding properties, coordinated by a η7-B7 ligand on one side and a BO ligand on the other.