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The Electrochemical Society, Journal of The Electrochemical Society, 6(168), p. 066501, 2021

DOI: 10.1149/1945-7111/ac0303

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Communication—Mg2+/0 as a Reliable Reference Electrode for Molten Chloride Salts

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

In this report, we describe the use of the Mg2+/0 couple as a reference in molten MgCl2-NaCl. We demonstrate that this redox couple provides a robust and reliable reference potential over a range of melt temperatures (500 °C–675 °C). Finally, we demonstrate the construction of a simple molten magnesium reference electrode, for operation at temperatures greater than the melting point of magnesium (650 °C).