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Thieme Gruppe, Synthesis: Journal of Synthetic Organic Chemistry, 21(54), p. 4703-4710, 2021

DOI: 10.1055/a-1588-0072

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Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Functionalization of Sulfoximines

Journal article published in 2021 by Tatsuhiko Yoshino ORCID, Shigeki Matsunaga ORCID, Long-Tao Huang, Yuki Hirata, Yoshimi Kato, Luqing Lin ORCID, Masahiro Kojima ORCID
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Abstract

AbstractRuthenium(II)-catalyzed enantioselective C–H functionalization reactions of sulfoximines with sulfoxonium ylides are described. The combination of [RuCl2(p-cymene)]2 and a pseudo-C 2-symmetric binaphthyl monocarboxylic acid furnished the S-chiral products in 76:24 to 92:8 er.