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Royal Society of Chemistry, Chemical Science, 20(12), p. 7066-7072, 2021

DOI: 10.1039/d1sc01349a

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Strain-release 2-azaallyl anion addition/borylation of [1.1.1]propellane: synthesis and functionalization of benzylamine bicyclo[1.1.1]pentyl boronates

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We report a 3-component reaction between N-benzyl ketimines, [1.1.1]propellane, and pinacol boronates to generate benzylamine bicyclo[1.1.1]pentane (BCP) pinacol boronates.