Published in
Royal Society of Chemistry, RSC Advances, 57(10), p. 34632-34650, 2020
DOI: 10.1039/d0ra07118h
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Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series
Journal article published in 2020 by
Devon L. Drey 
,
Eric C. O'Quinn,
Tamilarasan Subramani,
Kristina Lilova,
Gianguido Baldinozzi,
Igor M. Gussev,
Antonio F. Fuentes ,
Joerg C. Neuefeind,
Michelle Everett,
David Sprouster ,
Alexandra Navrotsky,
Rodney C. Ewing,
Maik Lang
,
Eric C. O'Quinn,
Tamilarasan Subramani,
Kristina Lilova,
Gianguido Baldinozzi,
Igor M. Gussev,
Antonio F. Fuentes ,
Joerg C. Neuefeind,
Michelle Everett,
David Sprouster ,
Alexandra Navrotsky,
Rodney C. Ewing,
Maik Lang
This paper is made freely available by the publisher.
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Abstract
Combined neutron and X-ray total scattering with calorimetric measurements of the solid solution series Ho2Ti2−xZrxO7 reveals a complex order–disorder transition across short, intermediate, and long length scales induced by chemical substitution.