Published in

Nature Research, Nature Communications, 1(12), 2021

DOI: 10.1038/s41467-021-21234-z

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High-efficiency magnetic refrigeration using holmium

Journal article published in 2021 by Noriki Terada ORCID, Hiroaki Mamiya ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

AbstractMagnetic refrigeration (MR) is a method of cooling matter using a magnetic field. Traditionally, it has been studied for use in refrigeration near room temperature; however, recently MR research has also focused on a target temperature as low as 20 K for hydrogen liquefaction. Most research to date has employed high magnetic fields (at least 5 T) to obtain a large entropy change, which requires a superconducting magnet and, therefore, incurs a large energy cost. Here we propose an alternative highly efficient cooling technique in which small magnetic field changes, Δμ0H ≤ 0.4 T, can obtain a cooling efficiency of −ΔSM/Δμ0H = 32 J kg−1K−1T−1, which is one order of magnitude higher than what has been achieved using typical magnetocaloric materials. Our method uses holmium, which exhibits a steep magnetization change with varying temperature and magnetic field. The proposed technique can be implemented using permanent magnets, making it a suitable alternative to conventional gas compression–based cooling for hydrogen liquefaction.