Poly(vinylidene fluoride), PVDF, and its copolymers exhibit interesting properties for being used as separator membranes in lithium-ion battery applications. This review presents the developments and summarizes the main characteristics of these materials for battery separator membranes. The review is divided into three categories regarding the composition of the polymer membranes: single polymers, polymer composites and polymer blends. For each category, the main characteristics for battery separator membranes and the ion transport behaviour is presented. Finally, guidelines for further investigations are outlined.