Published in
Royal Society of Chemistry, Chemical Science, 11(12), p. 3944-3951, 2021
DOI: 10.1039/d0sc06837c
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Translational dynamics of a non-degenerate molecular shuttle imbedded in a zirconium metal–organic framework
Journal article published in 2021 by
Benjamin H. Wilson,
Louae M. Abdulla,
Robert W. Schurko 
,
Stephen J. Loeb
,
Stephen J. Loeb
This paper is made freely available by the publisher.
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Abstract
An unsymmetrical molecular shuttle was incorporated into the octahedral cavities of a Zr(iv) MOF. 13C SSNMR showed that the presence of mesitylene in the pores results in an increase in the barriers for the thermally driven motion of the macrocycle.