World Scientific Publishing, Functional Materials Letters, 03(14), p. 2140001, 2021
DOI: 10.1142/s1793604721400014
Full text: Unavailable
Owing to their high ionic conductivity and excellent flexibility, composite polymer electrolytes (CPEs) have been widely studied in solid lithium metal batteries (SLMBs). In this study, a new solid electrolyte of NASICON-type Li3Zr2Si2[Formula: see text] (LZSP) was prepared by the sol–gel method, and then a new type of CPE membrane containing LZSP and Poly(vinylidene fluoride) (PVDF) was synthesized by slurry-casting method. The CPE membrane presented much higher ionic conductivity of 5.66 × 10[Formula: see text] S ⋅ cm[Formula: see text] at 25∘C and stronger electrochemical stability compared to the one without LZSP. In addition, the cells containing the composite electrolyte membrane exhibited considerable rate performance and cycle performance.