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Wiley, Advanced Synthesis & Catalysis, 1(354), p. 65-70, 2011

DOI: 10.1002/adsc.201100409

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Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes

Journal article published in 2011 by Isaac Garcia Bosch, Laura Gómez Martín ORCID, Alfonso Polo Ortiz, Xavi Ribas Salamaña ORCID, Miquel Costas Salgueiro ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Novel manganese complexes containing N4-tetradentate ligands derived from chiral bipyrrolidinediamines catalyze the stereoselective epoxidation of a wide array of alkenes using low catalyst loadings (0.1 mol%) and hydrogen peroxide (1.2 equiv.) as terminal oxidant. This family of catalysts affords good to excellent yields (80–100%) and moderate to good ees (40–73%) in short reaction times (30 min) making efficient use of hydrogen peroxide