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Wiley, European Journal of Organic Chemistry, 18(2010), p. 3507-03515, 2010

DOI: 10.1002/ejoc.201000046

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Aromatic Nitrogen Donors for Efficient Copper(I)-NHC CuAAC under reductant-free conditions.

Journal article published in 2010 by Marie-Laure Teyssot, Lionel Nauton, Jean-Louis Canet, Federico Cisnetti, Aurélien Chevry, Arnaud Gautier
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This paper is available in a repository.

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Abstract

Copper(I)-catalysed azide–alkyne cycloaddition (CuAAC) has been successfully conducted under reductant-free conditions. The catalytic system consisted of a combination of a copper(I)–N-heterocyclic carbene complex and aromatic N-donors. The catalyst is stable and can be stored, thus rendering the reaction valuable for routine use.