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Royal Society of Chemistry, Chemical Science, 8(12), p. 2823-2828, 2021
DOI: 10.1039/d0sc05408a
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Polyolefin Catalysis of Propene, 1-Butene and Isobutene Monitored Using Hyperpolarized NMR
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Abstract
Hyperpolarization by dissolution dynamic nuclear polarization (DNP) enhances 13C NMR signals of normally gaseous olefins. The polymerization reactions of these dissolved gases catalyzed by a metallocene catalyst are characterized in real time.