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Royal Society of Chemistry, Chemical Science, 6(12), p. 2268-2275, 2021

DOI: 10.1039/d0sc04949b

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Transition-metal-mediated reduction and reversible double-cyclization of cyanuric triazide to an asymmetric bitetrazolate involving cleavage of the six-membered aromatic ring

Journal article published in 2021 by Shivaiah Vaddypally ORCID, Vitaly G. Kiselev ORCID, Alex N. Byrne, C. Franklin Goldsmith ORCID, Michael John Zdilla ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Cyanuric triazide reacts with transition metal precursors, extruding N2 and reducing the ligand by two electrons, which breaks an aromatic ring and rearranges to a bitetrazolylmethanediiminate (biTzI2−) ligand, forming two new aromatic rings.