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Royal Society of Chemistry, Chemical Science, 3(12), p. 1016-1030, 2021

DOI: 10.1039/d0sc05281g

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Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

Journal article published in 2021 by Ana A. C. Pacheco, Arnaldo F. da Silva Filho, Kristoffer Kortsen ORCID, Magnus W. D. Hanson-Heine, Vincenzo Taresco ORCID, Jonathan D. Hirst ORCID, Muriel Lansalot ORCID, Franck D'Agosto ORCID, Steven M. Howdle ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

RAFT dispersion polymerisation of methyl methacrylate is performed in scCO2 with 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT) present as chain transfer agent (CTA) and surprisingly shows good control over PMMA molecular weight.