Royal Society of Chemistry, Chemical Science, 3(12), p. 1016-1030, 2021
DOI: 10.1039/d0sc05281g
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RAFT dispersion polymerisation of methyl methacrylate is performed in scCO2 with 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT) present as chain transfer agent (CTA) and surprisingly shows good control over PMMA molecular weight.