Urban air pollution continues to represent a primary concern for human health, despite significant efforts by public authorities for mitigating its effects. Regulatory monitoring networks are essential tools for air pollution monitoring. However, they are sparse networks, unable to capture the spatial variability of the air pollutants. For addressing this issue, networks of low cost stations are deployed, supplementing the regulatory stations. Regarding this application, an important question is where these stations are installed The objective of this study was to generate a site suitability map for the development of a network of low cost multi-sensor stations across a city for a spatially dense urban air quality monitoring. To do that, a site suitability analysis was developed based on two geographical variables properly selected for representing the impact of urban pollutant sources and urban form on the pollutant concentrations. By processing information about emissions patterns and street canyon effects, we were able to identify air quality hotspot areas supposed to show high spatial variability. Low cost monitoring stations, there located, are able to provide that informative content, which is lacking for both regulatory monitoring networks and predictive modelling for high resolution air quality mapping.