Published in
Royal Society of Chemistry, Chemical Science, 2(12), p. 569-575, 2021
DOI: 10.1039/d0sc05553k
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Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
Journal article published in 2020 by
Tao He 
,
Guoqiang Wang ,
Peng-Wei Long ,
Sebastian Kemper ,
Elisabeth Irran ,
Hendrik F. T. Klare ,
Martin Oestreich
,
Guoqiang Wang ,
Peng-Wei Long ,
Sebastian Kemper ,
Elisabeth Irran ,
Hendrik F. T. Klare ,
Martin Oestreich
This paper is made freely available by the publisher.
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Abstract
Downstream to alkene hydrosilylation, the opening of the cyclopropane ring in benzyl-substituted VCPs is interlinked with an SEAr of the aryl group.