Published in
Royal Society of Chemistry, Chemical Science, 45(11), p. 12364-12370, 2020
DOI: 10.1039/d0sc04244g
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Et3SiH + KOtBu Provide Multiple Reactive Intermediates that Compete in the Reactions and Rearrangements of Benzylnitriles and Indolenines
Journal article published in 2020 by
Andrew J. Smith,
Daniela Dimitrova,
Jude N. Arokianathar,
Kenneth F. Clark,
Darren L. Poole 
,
Stuart G. Leach,
John A. Murphy
,
Stuart G. Leach,
John A. Murphy
This paper is made freely available by the publisher.
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Abstract
The combination of potassium tert-butoxide and triethylsilane provides simultaneous access to multiple reactive intermediates, radicals, H-atom donors, hydride donors and electron donors, giving scope for unprecedented reaction outcomes.