Abstract MnO₂ nanomaterials were synthesized using a simple wet redox method. Crystal structure of as prepared pure and Al doped MnO₂ nanomaterials was investigated using X-ray diffraction (XRD) technique. Crystal structure was further confirmed by FTIR analysis. Morphology of pure MnO₂, Al doped MnO₂, MnO₂/CNT hybrid structure and Al doped MnO₂/CNT hybrid structure was studied using scanning electron microscopy (SEM). Energy dispersive X-ray spectroscopy confirmed the presence of all the constituent atoms in the crystal structure of all the samples. Bandgap value was found to decrease with the modification (doping and hybrid structure). Photocatalytic efficiency of all the MnO₂ samples was studied using the photodegradation of methylene blue (MB) under the visible light (solar radiation). Effect of different intermediates on the photodegradation efficiency was studied using different scavengers.