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Royal Society of Chemistry, Chemical Science, 37(11), p. 10175-10179, 2020

DOI: 10.1039/d0sc03216f

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Synthetic Methodology Towards Allylic Trans-Cyclooctene-Ethers Enables Modification of Carbohydrates: Bioorthogonal Manipulation of the Lac Repressor

Journal article published in 2020 by Mark A. R. de Geus ORCID, G. J. Mirjam Groenewold, Elmer Maurits, Can Araman ORCID, Sander I. van Kasteren ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Two novel reagents were developed to direct formation of allyliccis-cyclooctene (CCO) ethers, followed by photochemical isomerization to obtaintrans-cyclooctene (TCO) ethers. The method was used to cage a bio-active carbohydrate.