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Royal Society of Chemistry, Chemical Science, 32(11), p. 8600-8609, 2020

DOI: 10.1039/d0sc02413a

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Understanding the factors controlling the photo-oxidation of natural DNA by enantiomerically pure intercalating ruthenium polypyridyl complexes through TA/TRIR studies with polydeoxynucleotides and mixed sequence oligodeoxynucleotides

Journal article published in 2020 by Páraic M. Keane ORCID, Kyra O'Sullivan, Fergus E. Poynton, Bjørn C. Poulsen, Igor V. Sazanovich, Michael Towrie ORCID, Christine J. Cardin, Xue-Zhong Sun, Michael W. George ORCID, Thorfinnur Gunnlaugsson ORCID, Susan J. Quinn ORCID, John M. Kelly ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Efficient electron transfer requires the complex to be intercalated at a G-C base-pair. Identification of preferred intercalation sites is achieved by TRIR monitoring of the nucleobase vibrations before electron transfer.