In this study, a detailed investigation of the dynamics of the generation of pre-pulse by post-pulses is presented, using single-shot self-referenced spectral interferometry (SRSI). The capability of SRSI in terms of the single-shot measurement of the temporal contrast of high-power laser systems has been experimentally demonstrated. The results confirm that the energy levels of the pre-pulses increase proportional to the square of the B-integral parametrizing the nonlinearity of the amplifier chain.