Dissemin is shutting down on January 1st, 2025

Published in

American Physical Society, Physical review B, 14(90), 2014

DOI: 10.1103/physrevb.90.144104

Links

Tools

Export citation

Search in Google Scholar

Solidification and fcc to metastable hcp phase transition in krypton under variable compression rates

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Green circle
Published version: archiving allowed
Data provided by SHERPA/RoMEO

Abstract

We present time-resolved synchrotron x-ray diffraction measurements to study kinetics associated with theliquid-solid and solid-solid high-pressure phase transitions in Kr under dynamic loading in a dynamic-diamondanvil cell. The results show a strong compression-rate dependence of the solidification/melting process in liquidKr. The analysis of the compression-rate dependent melting/solidification, using an Avrami equation with theparameter n = 1, indicates a spontaneous nucleation and one-dimensional growth mechanism. In contrast, theface-centered-cubic to metastable hexagonal close-packed transition in solid Kr occurs rapidly at 0.8 GPa nearthemelting line, which has negligible compression-rate dependence within the range of compression rates studied(0.004–13 GPa/s).