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Elsevier, Carbon, 6(46), p. 931-939

DOI: 10.1016/j.carbon.2008.02.019

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Direct synthesis of graphitic carbon nanostructures from saccharides and their use as electrocatalytic supports

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This paper is available in a repository.

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Abstract

An easy method is described for fabricating graphitic carbon nanostructures (GCNs) from a variety of saccharides; i.e., a monosaccharide (glucose), a disaccharide (sucrose) and a polysaccharide (starch). The synthesis scheme consists of: (a) impregnation of saccharide with Ni or Fe nitrates, (b) heat treatment under inert atmosphere (N2) up to 900°C or 1000°C and (c) oxidation in liquid phase to selectively recover the graphitic carbon. This procedure leads to GCNs with a variety of morphologies: nanopipes nanocoils and nanocapsules. Such GCNs have a high crystallinity, as shown by TEM/SAED, XRD and Raman analysis. The GCNs were used as supports for platinum nanoparticles, which were well dispersed (Mean Pt size ~2–3 nm). Electrocatalysts thus prepared have electrocatalytic surface areas in the 70–95 m2 g−1 Pt range and exhibit high catalytic activities towards methanol electrooxidation. ; Financial support for this research work provided by the Spanish MCyT (MAT2005-00262, MAT2004-01479 and FEDER).