Published in
Royal Society of Chemistry, Chemical Science, 26(11), p. 6766-6774, 2020
DOI: 10.1039/d0sc02942d
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Ruthenium-catalyzed hydrogenation of CO2 as a route to methyl esters for use as biofuels or fine chemicals
Journal article published in 2020 by
Zheng Wang 
,
Ziwei Zhao,
Yong Li,
Yanxia Zhong,
Qiuyue Zhang ,
Qingbin Liu ,
Gregory A. Solan ,
Yanping Ma ,
Wen-Hua Sun
,
Ziwei Zhao,
Yong Li,
Yanxia Zhong,
Qiuyue Zhang ,
Qingbin Liu ,
Gregory A. Solan ,
Yanping Ma ,
Wen-Hua Sun
This paper is made freely available by the publisher.
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Abstract
A novel robust diphosphine–ruthenium(ii) complex has been developed that can efficiently catalyze both the hydrogenation of CO2 to methanol and its in situ condensation with carboxylic acids to give methyl esters.